Access to 1,1-Diborylalkenes and Concomitant Stereoselective Reactivity

Jordi Royes, Ana B. Cuenca, Elena Fernández

Producció científica: Article en revista indexadaArticle de revisió (sistemàtica)Avaluat per experts

39 Cites (Scopus)

Resum

Gem-diborylalkenes have emerged as efficient reagents for selective cross-coupling reactions, reduction approaches and Michael additions. The synthesis of 1,1-diborylalkenes involves condensation of polyborated compounds with aldehydes or ketones followed by B–O elimination, geminal diboration of 1,1-dihaloalkenes, 1-haloalkenes or terminal alkynes, dehydrogenative borylation of alkenes, borylation of alkynylboronates and hydroboration of alkynylboronates. These new sets of reactions are general for a wide range of substrates and they can be understood to have complementary mechanisms.

Idioma originalAnglès
Pàgines (de-a)2728-2739
Nombre de pàgines12
RevistaEuropean Journal of Organic Chemistry
Volum2018
Número22
DOIs
Estat de la publicacióPublicada - 15 de juny 2018

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