Access to 1,1-Diborylalkenes and Concomitant Stereoselective Reactivity

Jordi Royes, Ana B. Cuenca, Elena Fernández

Producción científica: Artículo en revista indizadaRecensiónrevisión exhaustiva

38 Citas (Scopus)

Resumen

Gem-diborylalkenes have emerged as efficient reagents for selective cross-coupling reactions, reduction approaches and Michael additions. The synthesis of 1,1-diborylalkenes involves condensation of polyborated compounds with aldehydes or ketones followed by B–O elimination, geminal diboration of 1,1-dihaloalkenes, 1-haloalkenes or terminal alkynes, dehydrogenative borylation of alkenes, borylation of alkynylboronates and hydroboration of alkynylboronates. These new sets of reactions are general for a wide range of substrates and they can be understood to have complementary mechanisms.

Idioma originalInglés
Páginas (desde-hasta)2728-2739
Número de páginas12
PublicaciónEuropean Journal of Organic Chemistry
Volumen2018
N.º22
DOI
EstadoPublicada - 15 jun 2018

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