Resumen
The thermal decomposition of tricyclohexylidene triperoxide both pure and in 4% w/w solution of n-dodecane to yield mainly 16-hexadecanolide is studied applying the nonparametric kinetics method to a set of scanning calorimetry records. The apparent energies of activation obtained are 148.4 ± 0.8 and 90.9 ± 0.8 kJ mol−1, respectively. Combined kinetic models are proposed (first order + Šesták–Berggren) to describe the processes. The isothermal decomposition of the pure peroxide is studied, indicating that there is no appreciable reaction after 12 h at temperatures below 103 °C and that conversion is complete at temperatures over 137 °C.
Idioma original | Inglés |
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Páginas (desde-hasta) | 1293-1298 |
Número de páginas | 6 |
Publicación | Journal of Thermal Analysis and Calorimetry |
Volumen | 134 |
N.º | 2 |
DOI | |
Estado | Publicada - 1 nov 2018 |