Thermal decomposition of tricyclohexylidene triperoxide

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Resum

The thermal decomposition of tricyclohexylidene triperoxide both pure and in 4% w/w solution of n-dodecane to yield mainly 16-hexadecanolide is studied applying the nonparametric kinetics method to a set of scanning calorimetry records. The apparent energies of activation obtained are 148.4 ± 0.8 and 90.9 ± 0.8 kJ mol−1, respectively. Combined kinetic models are proposed (first order + Šesták–Berggren) to describe the processes. The isothermal decomposition of the pure peroxide is studied, indicating that there is no appreciable reaction after 12 h at temperatures below 103 °C and that conversion is complete at temperatures over 137 °C.

Idioma originalAnglès
Pàgines (de-a)1293-1298
Nombre de pàgines6
RevistaJournal of Thermal Analysis and Calorimetry
Volum134
Número2
DOIs
Estat de la publicacióPublicada - 1 de nov. 2018

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