Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

Antoni Planas; Jaime Tomás; Juan Julio Bonet

doi:10.1016/S0040-4039(00)95759-9

Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

Antoni Planas, Jaime Tomás, Juan Julio Bonet

Departament de Bioenginyeria

Producció científica: Article en revista indexada › Article › Avaluat per experts

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Resum

The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.

Idioma original	Anglès
Pàgines (de-a)	471-474
Nombre de pàgines	4
Revista	Tetrahedron Letters
Volum	28
Número	4
DOIs	https://doi.org/10.1016/S0040-4039(00)95759-9
Estat de la publicació	Publicada - 1987

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@article{57006e2fcdbb4c0fa81f18472e817bbc,

title = "Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols",

abstract = "The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.",

author = "Antoni Planas and Jaime Tom{\'a}s and Bonet, {Juan Julio}",

year = "1987",

doi = "10.1016/S0040-4039(00)95759-9",

language = "English",

volume = "28",

pages = "471--474",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd.",

number = "4",

}

TY - JOUR

T1 - Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

AU - Planas, Antoni

AU - Tomás, Jaime

AU - Bonet, Juan Julio

PY - 1987

Y1 - 1987

N2 - The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.

AB - The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.

UR - http://www.scopus.com/inward/record.url?scp=0023086319&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)95759-9

DO - 10.1016/S0040-4039(00)95759-9

M3 - Article

AN - SCOPUS:0023086319

SN - 0040-4039

VL - 28

SP - 471

EP - 474

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 4

ER -

Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

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