Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

Antoni Planas; Jaime Tomás; Juan Julio Bonet

doi:10.1016/S0040-4039(00)95759-9

Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

Antoni Planas^*, Jaime Tomás, Juan Julio Bonet

^*Corresponding author for this work

Bioengineering Department

Research output: Indexed journal article › Article › peer-review

14 Citations (Scopus)

Abstract

The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.

Original language	English
Pages (from-to)	471-474
Number of pages	4
Journal	Tetrahedron Letters
Volume	28
Issue number	4
DOIs	https://doi.org/10.1016/S0040-4039(00)95759-9
Publication status	Published - 1987

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10.1016/S0040-4039(00)95759-9

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title = "Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols",

abstract = "The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.",

author = "Antoni Planas and Jaime Tom{\'a}s and Bonet, {Juan Julio}",

year = "1987",

doi = "10.1016/S0040-4039(00)95759-9",

language = "English",

volume = "28",

pages = "471--474",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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T1 - Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

AU - Planas, Antoni

AU - Tomás, Jaime

AU - Bonet, Juan Julio

PY - 1987

Y1 - 1987

N2 - The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.

AB - The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.

UR - http://www.scopus.com/inward/record.url?scp=0023086319&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)95759-9

DO - 10.1016/S0040-4039(00)95759-9

M3 - Article

AN - SCOPUS:0023086319

SN - 0040-4039

VL - 28

SP - 471

EP - 474

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 4

ER -

Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

Abstract

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