Fundamental data: Solubility of nickel and oxygen and diffusivity of iron and oxygen in molten LBE

J. Abella; A. Verdaguer; S. Colominas; K. Ginestar; L. Martinelli

doi:10.1016/j.jnucmat.2011.04.036

Fundamental data: Solubility of nickel and oxygen and diffusivity of iron and oxygen in molten LBE

J. Abella, A. Verdaguer, S. Colominas, K. Ginestar, L. Martinelli

IQS School of Engineering

Producción científica: Artículo en revista indizada › Artículo › revisión exhaustiva

21 Citas (Scopus)

Resumen

Experiments for determining nickel solubility limit and iron diffusion coefficient are presented and their results are discussed. Nickel solubility limit is determined by two methods: ex situ by solid sampling followed by ICP-AES analysis and in situ by Laser Induced Breakdown Spectroscopy and their results are compared. The iron diffusion coefficient is obtained using the technique of rotating specimen dissolution. Also a method to determine the oxygen solubility and diffusivity in LBE is developed and results at 460, 500 and 540 °C are presented. It is based on the following electrochemical cell: O₂ (reference mixture), Pt //YSZ//O₂ (LBE) which can work as an oxygen sensor or as a coulometric pump.

Idioma original	Inglés
Páginas (desde-hasta)	329-337
Número de páginas	9
Publicación	Journal of Nuclear Materials
Volumen	415
N.º	3
DOI	https://doi.org/10.1016/j.jnucmat.2011.04.036
Estado	Publicada - 31 ago 2011

Acceder al documento

10.1016/j.jnucmat.2011.04.036

Otros archivos y enlaces

Enlace a la publicación en Scopus

Citar esto

@article{0ec38622f54945868a7846836662a9f8,

title = "Fundamental data: Solubility of nickel and oxygen and diffusivity of iron and oxygen in molten LBE",

abstract = "Experiments for determining nickel solubility limit and iron diffusion coefficient are presented and their results are discussed. Nickel solubility limit is determined by two methods: ex situ by solid sampling followed by ICP-AES analysis and in situ by Laser Induced Breakdown Spectroscopy and their results are compared. The iron diffusion coefficient is obtained using the technique of rotating specimen dissolution. Also a method to determine the oxygen solubility and diffusivity in LBE is developed and results at 460, 500 and 540 °C are presented. It is based on the following electrochemical cell: O2 (reference mixture), Pt //YSZ//O2 (LBE) which can work as an oxygen sensor or as a coulometric pump.",

author = "J. Abella and A. Verdaguer and S. Colominas and K. Ginestar and L. Martinelli",

year = "2011",

month = aug,

day = "31",

doi = "10.1016/j.jnucmat.2011.04.036",

language = "English",

volume = "415",

pages = "329--337",

journal = "Journal of Nuclear Materials",

issn = "0022-3115",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Fundamental data

T2 - Solubility of nickel and oxygen and diffusivity of iron and oxygen in molten LBE

AU - Abella, J.

AU - Verdaguer, A.

AU - Colominas, S.

AU - Ginestar, K.

AU - Martinelli, L.

PY - 2011/8/31

Y1 - 2011/8/31

N2 - Experiments for determining nickel solubility limit and iron diffusion coefficient are presented and their results are discussed. Nickel solubility limit is determined by two methods: ex situ by solid sampling followed by ICP-AES analysis and in situ by Laser Induced Breakdown Spectroscopy and their results are compared. The iron diffusion coefficient is obtained using the technique of rotating specimen dissolution. Also a method to determine the oxygen solubility and diffusivity in LBE is developed and results at 460, 500 and 540 °C are presented. It is based on the following electrochemical cell: O2 (reference mixture), Pt //YSZ//O2 (LBE) which can work as an oxygen sensor or as a coulometric pump.

AB - Experiments for determining nickel solubility limit and iron diffusion coefficient are presented and their results are discussed. Nickel solubility limit is determined by two methods: ex situ by solid sampling followed by ICP-AES analysis and in situ by Laser Induced Breakdown Spectroscopy and their results are compared. The iron diffusion coefficient is obtained using the technique of rotating specimen dissolution. Also a method to determine the oxygen solubility and diffusivity in LBE is developed and results at 460, 500 and 540 °C are presented. It is based on the following electrochemical cell: O2 (reference mixture), Pt //YSZ//O2 (LBE) which can work as an oxygen sensor or as a coulometric pump.

UR - http://www.scopus.com/inward/record.url?scp=80052021825&partnerID=8YFLogxK

U2 - 10.1016/j.jnucmat.2011.04.036

DO - 10.1016/j.jnucmat.2011.04.036

M3 - Article

AN - SCOPUS:80052021825

SN - 0022-3115

VL - 415

SP - 329

EP - 337

JO - Journal of Nuclear Materials

JF - Journal of Nuclear Materials

IS - 3

ER -

Fundamental data: Solubility of nickel and oxygen and diffusivity of iron and oxygen in molten LBE

Resumen

Acceder al documento

Otros archivos y enlaces

Huella

Citar esto