TY - JOUR
T1 - High-consistency silicone rubber with reduced Young's modulus. An industrial option to dielectric silicone rubber
AU - Rius-Bartra, Joaquim Mª
AU - Ferrer-Serrano, Norma
AU - Agulló, Núria
AU - Borrós, Salvador
N1 - Publisher Copyright:
© 2023 The Authors. Journal of Applied Polymer Science published by Wiley Periodicals LLC.
PY - 2023
Y1 - 2023
N2 - Flexible capacitive sensors based on silicone rubber have gained importance in both academic and industrial fields due to their advantages, including low power consumption and high stability to temperature, and humidity. However, pristine silicone rubber has a low dielectric constant ((Formula presented.)), requiring the use of dielectric additives such as TiO2, BaTiO3, or Sb2O3-doped SnO2 rutile-modified particles (ATO) to enhance electrical properties, but they also increase Young's modulus (E). To overcome this problem, liquid silicone rubbers (LSR) are commonly used in academic research due to their low E, but they often compromise mechanical integrity. In contrast, high-consistency silicone rubbers (HCR), the industry commodity, maintain mechanical integrity even at high filler loadings but are limited in their use in dielectrics due to high E values. This paper explores the potential of vinyl-terminated HCR for developing dielectric composites with high electromechanical response, with an improved (Formula presented.) and a reduced E while retaining mechanical and processability properties. The resulting dielectric HCR formulations exhibit optimal properties for developing flexible capacitive sensors using well-established industrial products and processes.
AB - Flexible capacitive sensors based on silicone rubber have gained importance in both academic and industrial fields due to their advantages, including low power consumption and high stability to temperature, and humidity. However, pristine silicone rubber has a low dielectric constant ((Formula presented.)), requiring the use of dielectric additives such as TiO2, BaTiO3, or Sb2O3-doped SnO2 rutile-modified particles (ATO) to enhance electrical properties, but they also increase Young's modulus (E). To overcome this problem, liquid silicone rubbers (LSR) are commonly used in academic research due to their low E, but they often compromise mechanical integrity. In contrast, high-consistency silicone rubbers (HCR), the industry commodity, maintain mechanical integrity even at high filler loadings but are limited in their use in dielectrics due to high E values. This paper explores the potential of vinyl-terminated HCR for developing dielectric composites with high electromechanical response, with an improved (Formula presented.) and a reduced E while retaining mechanical and processability properties. The resulting dielectric HCR formulations exhibit optimal properties for developing flexible capacitive sensors using well-established industrial products and processes.
KW - capacitive sensors
KW - dielectric constant
KW - electroactive polymers
KW - flexible sensors
KW - high-consistency silicone rubbers
KW - liquid silicone rubbers
KW - transductors
UR - http://www.scopus.com/inward/record.url?scp=85165251250&partnerID=8YFLogxK
U2 - 10.1002/app.54405
DO - 10.1002/app.54405
M3 - Article
AN - SCOPUS:85165251250
SN - 0021-8995
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
ER -