TY - JOUR
T1 - A hexaco-ordinate platinum complex containing four Pt-Sn bonds, one of them to SnII
AU - Almeida, Joaquim F.
AU - Dixon, Keith R.
AU - Eaborn, Colin
AU - Hitchcock, Peter B.
AU - Pidcock, Alan
AU - Vinaixa, Jordi
N1 - Funding Information:
We thank the S.E.R.C. for partial support of this work (viaC.E.), the University of Victoria for study leave funding (K.R.D.), the Caixa de Barcelona for a research fellowship (J.V.), and the Instituto Nacional de Investigaqiio Cientifica (Portugal) for financial support (J.F.A.). Received, 4th Scptemher I982; Corn. 1064 References 1 C. Eaborn, A. Pidcock, and B. R. Steele, J. Chern. Soc., Ddtun Tran.v., 1975, 809; J. F. Almeida, H. Aziiian, C. Eaborn, and A. Pidcock, J. Organornet. Chem., 1981, 210, 121. 2 C. Eaborn, K. Kundu, and A. Pidcock, J. Chem. Soc., Dalton Trans., 1981, 1223, and references therein; T. A. K. Al-Allaf, C. Eaborn, K. Kundu, and A. Pidcock, J. Chem Soc., Ckem. Commun., 1981, 55.
PY - 1982
Y1 - 1982
N2 - The complex [Pt(CO3)(SEt2)(PEt3)] reacts readily with SnR3H (R = p-MeC6H4) in MeOH to give a hexaco-ordinate PtIV complex in which the ligands are PEt 3, H (these two being trans to one another), R3Sn IV, R2SnII, and 2 × R2(MeO) SnIV, with the OMe groups of the last ligands bridging to the R 2SnII centre; the four Sn and two O atoms lie approximately in a plane, with the Pt atom 0.48 Å out of this plane towards the PEt3 ligand.
AB - The complex [Pt(CO3)(SEt2)(PEt3)] reacts readily with SnR3H (R = p-MeC6H4) in MeOH to give a hexaco-ordinate PtIV complex in which the ligands are PEt 3, H (these two being trans to one another), R3Sn IV, R2SnII, and 2 × R2(MeO) SnIV, with the OMe groups of the last ligands bridging to the R 2SnII centre; the four Sn and two O atoms lie approximately in a plane, with the Pt atom 0.48 Å out of this plane towards the PEt3 ligand.
UR - http://www.scopus.com/inward/record.url?scp=37049110665&partnerID=8YFLogxK
U2 - 10.1039/C39820001315
DO - 10.1039/C39820001315
M3 - Article
AN - SCOPUS:37049110665
SN - 0022-4936
SP - 1315
EP - 1316
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 22
ER -