TY - JOUR
T1 - Synthesis and crystal structure of 1,3-bis(5-formylpyrrol-2-yl)benzene and its conversion to a macrocyclic derivative
AU - Şener, M. Kasim
AU - Sanchez-Garcia, David
AU - Akkurt, Mehmet
AU - Yildirim, Sema Öztürk
AU - Fun, Hoong Kun
AU - Sessler, Jonathan L.
PY - 2006
Y1 - 2006
N2 - This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, 13C NMR, and 1H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P21/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) Å, β = 105.892(2)°, V = 1291.00(9) Å3, and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.
AB - This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, 13C NMR, and 1H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P21/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) Å, β = 105.892(2)°, V = 1291.00(9) Å3, and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.
KW - Bisformylpyrrole
KW - Crystal structure
KW - Macrocycle
KW - Schiff Base
UR - http://www.scopus.com/inward/record.url?scp=33745921760&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33745921760
SN - 1300-0527
VL - 30
SP - 243
EP - 251
JO - Turkish Journal of Chemistry
JF - Turkish Journal of Chemistry
IS - 2
ER -