Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster; Qing He; Gonzalo Anguera; Matthew D. Moore; Xian Sheng Ke; Vincent M. Lynch; Jonathan L. Sessler

doi:10.1039/c7cc01674c

Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster, Qing He, Gonzalo Anguera, Matthew D. Moore, Xian Sheng Ke, Vincent M. Lynch, Jonathan L. Sessler^*

^*Autor/a de correspondencia de este trabajo

Producción científica: Artículo en revista indizada › Artículo › revisión exhaustiva

32 Citas (Scopus)

Resumen

The reaction between non-aqueous uranyl silylamide (UO₂[N(SiMe₃)₂]₂·2THF) under anaerobic conditions or uranyl acetate (UO₂(OAc)₂·2H₂O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

Idioma original	Inglés
Páginas (desde-hasta)	4981-4984
Número de páginas	4
Publicación	Chemical Communications
Volumen	53
N.º	36
DOI	https://doi.org/10.1039/c7cc01674c
Estado	Publicada - 2017
Publicado de forma externa	Sí

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title = "Synthesis and characterization of a dipyriamethyrin-uranyl complex",

abstract = "The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.",

author = "Brewster, {James T.} and Qing He and Gonzalo Anguera and Moore, {Matthew D.} and Ke, {Xian Sheng} and Lynch, {Vincent M.} and Sessler, {Jonathan L.}",

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doi = "10.1039/c7cc01674c",

language = "English",

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AU - Brewster, James T.

AU - He, Qing

AU - Anguera, Gonzalo

AU - Moore, Matthew D.

AU - Ke, Xian Sheng

AU - Lynch, Vincent M.

AU - Sessler, Jonathan L.

PY - 2017

Y1 - 2017

N2 - The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

AB - The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

UR - http://www.scopus.com/inward/record.url?scp=85021661440&partnerID=8YFLogxK

U2 - 10.1039/c7cc01674c

DO - 10.1039/c7cc01674c

M3 - Article

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AN - SCOPUS:85021661440

SN - 1359-7345

VL - 53

SP - 4981

EP - 4984

JO - Chemical Communications

JF - Chemical Communications

IS - 36

ER -

Synthesis and characterization of a dipyriamethyrin-uranyl complex

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