P.E.HSQMBC: Simultaneous measurement of proton-proton and proton-carbon coupling constants

Josep Saurí, Pau Nolis, Laura Castañar, Albert Virgili, Teodor Parella

Producción científica: Artículo en revista indizadaArtículorevisión exhaustiva

13 Citas (Scopus)

Resumen

A long-range optimized P.E.HSQC experiment, named P.E.HSQMBC, is proposed for the simultaneous measurement of a complete set of homonuclear and heteronuclear coupling constants from a single 2D cross-peak. The sign and the magnitude of proton-proton coupling constants are measured along the direct dimension from the relative E.COSY-type multiplet pattern displacement due to the passive one-bond coupling constant splitting generated in the indirect dimension. On the other hand, long-range proton-carbon coupling constants are independently determined in the detected dimension from a traditional fitting analysis of antiphase multiplet patterns or, more conveniently, from the IPAP multiplet displacement obtained from extended HSQMBC experiments.

Idioma originalInglés
Páginas (desde-hasta)101-106
Número de páginas6
PublicaciónJournal of Magnetic Resonance
Volumen224
DOI
EstadoPublicada - nov 2012
Publicado de forma externa

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