One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes

David Sánchez-García; José I. Borrell; Santi Nonell

doi:10.1021/ol802380g

One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes

David Sánchez-García^*
, José I. Borrell
, Santi Nonell

^*Autor/a de correspondencia de este trabajo

Producción científica: Artículo en revista indizada › Artículo › revisión exhaustiva

55 Citas (Scopus)

Resumen

A one-pot reaction for the synthesis of 4,4'-diaryl-and 4,4'-diheteroaryl-substituted 2,2'-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2'-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.

Idioma original	Inglés
Páginas (desde-hasta)	77-79
Número de páginas	3
Publicación	Organic Letters
Volumen	11
N.º	1
DOI	https://doi.org/10.1021/ol802380g
Estado	Publicada - 1 ene 2009

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abstract = "A one-pot reaction for the synthesis of 4,4'-diaryl-and 4,4'-diheteroaryl-substituted 2,2'-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2'-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.",

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author = "David S{\'a}nchez-Garc{\'i}a and Borrell, \{Jos{\'e} I.\} and Santi Nonell",

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doi = "10.1021/ol802380g",

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T1 - One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes

AU - Sánchez-García, David

AU - Borrell, José I.

AU - Nonell, Santi

PY - 2009/1/1

Y1 - 2009/1/1

N2 - A one-pot reaction for the synthesis of 4,4'-diaryl-and 4,4'-diheteroaryl-substituted 2,2'-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2'-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.

AB - A one-pot reaction for the synthesis of 4,4'-diaryl-and 4,4'-diheteroaryl-substituted 2,2'-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2'-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.

KW - Photodynamic therapy

KW - Chemistry

UR - https://www.scopus.com/pages/publications/59649094199

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One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes

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