TY - JOUR
T1 - Gold(I)-catalysed cascade reactions in the synthesis of 2,3-fused indole derivatives
AU - Gimeno, Ana
AU - Rodríguez-Gimeno, Alejandra
AU - Cuenca, Ana B.
AU - Ramírez De Arellano, Carmen
AU - Medio-Simón, Mercedes
AU - Asensio, Gregorio
N1 - Publisher Copyright:
© The Royal Society of Chemistry 2015.
PY - 2015/8/11
Y1 - 2015/8/11
N2 - A gold(I)-catalysed hydroaminative/arylative cascade for the efficient synthesis of a variety of indole-fused skeletons has been developed. Factors controlling the catalyst loading required in these transformations involving 1,3-unsubstituted indole intermediates have been revealed, allowing isolation of an unprecedented 1,3-dimetallated 3H-indole gold complex characterized by X-ray diffraction.
AB - A gold(I)-catalysed hydroaminative/arylative cascade for the efficient synthesis of a variety of indole-fused skeletons has been developed. Factors controlling the catalyst loading required in these transformations involving 1,3-unsubstituted indole intermediates have been revealed, allowing isolation of an unprecedented 1,3-dimetallated 3H-indole gold complex characterized by X-ray diffraction.
KW - Nonrearranged monoterpenoid unit
KW - Active carbazole alkaloids
KW - Gold-catalyzed synthesis
KW - One-pot synthesis
KW - Intermolecular hydroarylation
KW - Intramolecular hydroarylation
KW - Palladium(ii) complexes
KW - Unactivated alkenes
KW - Cyclization
KW - Activation
UR - https://www.scopus.com/pages/publications/84937806509
UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=pure_univeritat_ramon_llull&SrcAuth=WosAPI&KeyUT=WOS:000358346600010&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.1039/c5cc04606h
DO - 10.1039/c5cc04606h
M3 - Article
C2 - 26140354
AN - SCOPUS:84937806509
SN - 1359-7345
VL - 51
SP - 12384
EP - 12387
JO - Chemical Communications
JF - Chemical Communications
IS - 62
ER -