Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster, Qing He, Gonzalo Anguera, Matthew D. Moore, Xian Sheng Ke, Vincent M. Lynch, Jonathan L. Sessler

Research output: Indexed journal article Articlepeer-review

28 Citations (Scopus)

Abstract

The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

Original languageEnglish
Pages (from-to)4981-4984
Number of pages4
JournalChemical Communications
Volume53
Issue number36
DOIs
Publication statusPublished - 2017
Externally publishedYes

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