Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster; Qing He; Gonzalo Anguera; Matthew D. Moore; Xian Sheng Ke; Vincent M. Lynch; Jonathan L. Sessler

doi:10.1039/c7cc01674c

Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster, Qing He, Gonzalo Anguera, Matthew D. Moore, Xian Sheng Ke, Vincent M. Lynch, Jonathan L. Sessler^*

^*Corresponding author for this work

Research output: Indexed journal article › Article › peer-review

32 Citations (Scopus)

Abstract

The reaction between non-aqueous uranyl silylamide (UO₂[N(SiMe₃)₂]₂·2THF) under anaerobic conditions or uranyl acetate (UO₂(OAc)₂·2H₂O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

Original language	English
Pages (from-to)	4981-4984
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	36
DOIs	https://doi.org/10.1039/c7cc01674c
Publication status	Published - 2017
Externally published	Yes

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title = "Synthesis and characterization of a dipyriamethyrin-uranyl complex",

abstract = "The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.",

author = "Brewster, {James T.} and Qing He and Gonzalo Anguera and Moore, {Matthew D.} and Ke, {Xian Sheng} and Lynch, {Vincent M.} and Sessler, {Jonathan L.}",

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AU - Brewster, James T.

AU - He, Qing

AU - Anguera, Gonzalo

AU - Moore, Matthew D.

AU - Ke, Xian Sheng

AU - Lynch, Vincent M.

AU - Sessler, Jonathan L.

PY - 2017

Y1 - 2017

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AB - The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

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U2 - 10.1039/c7cc01674c

DO - 10.1039/c7cc01674c

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VL - 53

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JO - Chemical Communications

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ER -

Synthesis and characterization of a dipyriamethyrin-uranyl complex

Abstract

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