Porphycenes: Synthesis and derivatives

David Sánchez García, Jonathan L. Sessler*

*Corresponding author for this work

Research output: Indexed journal article Articlepeer-review

176 Citations (Scopus)

Abstract

Porphycene is an aromatic macrocycle and a constitutional isomer of porphyrin. It and its derivatives display unique physical and optical properties, including strong absorptions in the red region of the UV-vis spectrum. These features have made porphycene and porphycene analogues appealing molecules for use in biomedical applications and in the design of new materials. This critical review provides a concise overview of the most important syntheses of porphycenes, as well as those of various functionalized derivatives and heteroatom containing analogues. (95 references.).

Original languageEnglish
Pages (from-to)215-232
Number of pages18
JournalChemical Society Reviews
Volume37
Issue number1
DOIs
Publication statusPublished - 17 Dec 2008
Externally publishedYes

Keywords

  • Ligand-binding properties
  • Photodynamic therapy
  • Iron porphycene
  • O-2 binding
  • Porphyrinoid macrocycles
  • Photophysical properties
  • Myoglobin
  • Tetraphenylporphycene
  • Sapphyrins
  • Complexes

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