TY - GEN
T1 - Model of alkaline hydrolysis of chloroform with soda
AU - Sempere, J.
AU - Nomen, R.
AU - Cano, J.
PY - 2005
Y1 - 2005
N2 - Mixtures of chloroform and alkalis produce alkaline chlorides, formiates, and CO through a strongly exothermic set of reactions. The main problems of the synthetic procedure are a very high exothermic behavior shown by the chemical reactions, the formation of CO, and the two phase character of the reaction showing a strong dependence on stirring. Experiments in runway and non-runaway conditions have been carried out and the model that describes this complex reaction has been adjusted. When the temperature increases, the reaction rate also increases following two different tendencies. The stirring rate produces the same effects in the reaction rate. This is an abstract of a paper presented at the 7th World Congress of Chemical Engineering (Glasgow, Scotland 7/10-14/2005).
AB - Mixtures of chloroform and alkalis produce alkaline chlorides, formiates, and CO through a strongly exothermic set of reactions. The main problems of the synthetic procedure are a very high exothermic behavior shown by the chemical reactions, the formation of CO, and the two phase character of the reaction showing a strong dependence on stirring. Experiments in runway and non-runaway conditions have been carried out and the model that describes this complex reaction has been adjusted. When the temperature increases, the reaction rate also increases following two different tendencies. The stirring rate produces the same effects in the reaction rate. This is an abstract of a paper presented at the 7th World Congress of Chemical Engineering (Glasgow, Scotland 7/10-14/2005).
UR - http://www.scopus.com/inward/record.url?scp=33645152136&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:33645152136
SN - 0852954948
SN - 9780852954942
T3 - 7th World Congress of Chemical Engineering, GLASGOW2005, incorporating the 5th European Congress of Chemical Engineering
SP - 260
BT - 7th World Congress of Chemical Engineering, GLASGOW2005, incorporating the 5th European Congress of Chemical Engineering - Congress Manuscripts
T2 - 7th World Congress of Chemical Engineering, GLASGOW2005, incorporating the 5th European Congress of Chemical Engineering
Y2 - 10 July 2005 through 14 July 2005
ER -