Mixed diboration of alkenes in a metal-free context

Nuria Miralles; Jessica Cid; Ana B. Cuenca; Jorge J. Carbó; Elena Fernández

doi:10.1039/c4cc08743g

Mixed diboration of alkenes in a metal-free context

Nuria Miralles, Jessica Cid, Ana B. Cuenca, Jorge J. Carbó^*, Elena Fernández

^*Corresponding author for this work

Research output: Indexed journal article › Article › peer-review

79 Citations (Scopus)

Abstract

Experimental and theoretical rationalization on regioselective mixed diboration of alkenes, with the unsymmetrical diboron reagent Bpin-Bdan, providing the protecting Bdan moiety in the internal position.

Original language	English
Pages (from-to)	1693-1696
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	9
DOIs	https://doi.org/10.1039/c4cc08743g
Publication status	Published - 31 Jan 2015
Externally published	Yes

Keywords

Catalyzed enantioselective diboration
Boron conjugate addition
N-heterocyclic carbenes
Platinum(0)-catalyzed diboration
Asymmetric-synthesis
Alkynes
Diboron
Activation
Efficient
Borylation

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title = "Mixed diboration of alkenes in a metal-free context",

abstract = "Experimental and theoretical rationalization on regioselective mixed diboration of alkenes, with the unsymmetrical diboron reagent Bpin-Bdan, providing the protecting Bdan moiety in the internal position.",

keywords = "Catalyzed enantioselective diboration, Boron conjugate addition, N-heterocyclic carbenes, Platinum(0)-catalyzed diboration, Asymmetric-synthesis, Alkynes, Diboron, Activation, Efficient, Borylation",

author = "Nuria Miralles and Jessica Cid and Cuenca, {Ana B.} and Carb{\'o}, {Jorge J.} and Elena Fern{\'a}ndez",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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doi = "10.1039/c4cc08743g",

language = "English",

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T1 - Mixed diboration of alkenes in a metal-free context

AU - Miralles, Nuria

AU - Cid, Jessica

AU - Cuenca, Ana B.

AU - Carbó, Jorge J.

AU - Fernández, Elena

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/1/31

Y1 - 2015/1/31

N2 - Experimental and theoretical rationalization on regioselective mixed diboration of alkenes, with the unsymmetrical diboron reagent Bpin-Bdan, providing the protecting Bdan moiety in the internal position.

AB - Experimental and theoretical rationalization on regioselective mixed diboration of alkenes, with the unsymmetrical diboron reagent Bpin-Bdan, providing the protecting Bdan moiety in the internal position.

KW - Catalyzed enantioselective diboration

KW - Boron conjugate addition

KW - N-heterocyclic carbenes

KW - Platinum(0)-catalyzed diboration

KW - Asymmetric-synthesis

KW - Alkynes

KW - Diboron

KW - Activation

KW - Efficient

KW - Borylation

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JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Mixed diboration of alkenes in a metal-free context

Abstract

Keywords

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