Gram-Scale Synthesis of a Bench-Stable 5,5″-Unsubstituted Terpyrrole

James T. Brewster, Hadiqa Zafar, Matthew McVeigh, Christopher D. Wight, Gonzalo Anguera, Axel Steinbrück, Vincent M. Lynch, Jonathan L. Sessler

Research output: Indexed journal article Articlepeer-review

7 Citations (Scopus)

Abstract

The controlled preparation of higher order oligopyrrolic species holds broad utility across the chemical and material sciences. Here, we describe the gram-scale synthesis of a bench-stable 5,5″-unsubstituted terpyrrole in excellent yield via a tandem Suzuki cross-coupling with in situ deprotection. The solution and solid-state stability as well as UV-vis, fluorescence, and single crystal X-ray diffraction structure are also detailed.

Original languageEnglish
Pages (from-to)9568-9570
Number of pages3
JournalJournal of Organic Chemistry
Volume83
Issue number16
DOIs
Publication statusPublished - 17 Aug 2018
Externally publishedYes

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