Gold(I)-catalysed cascade reactions in the synthesis of 2,3-fused indole derivatives

Ana Gimeno, Alejandra Rodríguez-Gimeno, Ana B. Cuenca, Carmen Ramírez De Arellano, Mercedes Medio-Simón, Gregorio Asensio

Research output: Indexed journal article Articlepeer-review

23 Citations (Scopus)

Abstract

A gold(I)-catalysed hydroaminative/arylative cascade for the efficient synthesis of a variety of indole-fused skeletons has been developed. Factors controlling the catalyst loading required in these transformations involving 1,3-unsubstituted indole intermediates have been revealed, allowing isolation of an unprecedented 1,3-dimetallated 3H-indole gold complex characterized by X-ray diffraction.

Original languageEnglish
Pages (from-to)12384-12387
Number of pages4
JournalChemical Communications
Volume51
Issue number62
DOIs
Publication statusPublished - 11 Aug 2015
Externally publishedYes

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