Functionalized ordered mesoporous silicas (MCM-41): Synthesis and applications in catalysis

Gabriel Martínez-Edo; Alba Balmori; Iris Pontón Baroso; Andrea Martí Del Rio; David Sánchez García

doi:10.3390/catal8120617

Functionalized ordered mesoporous silicas (MCM-41): Synthesis and applications in catalysis

Gabriel Martínez-Edo
, Alba Balmori
, Iris Pontón Baroso
, Andrea Martí Del Rio
, David Sánchez García^*

^*Corresponding author for this work

Research output: Indexed journal article › Review › peer-review

157 Citations (Scopus)

Abstract

Mesoporous silica sieves are among the most studied nano-objects due to their stable pore structure and easy preparation. In particular, MCM-41 have attracted increasing research attention due to their chemical versatility. This review focuses on the synthesis and regioselective functionalization of MCM-41 to prepare catalytic systems. The topics covered are: mono and di-functionalized MCM-41 as basic and acid catalysts, catalysts based on metallic complexes and heteropolyacids supported onto MCM-41, metallic nanoparticles embed onto functionalized MCM-41 and magnetic MCM-41 for catalytic purposes.

Original language	English
Article number	617
Number of pages	62
Journal	Catalysts
Volume	8
Issue number	12
DOIs	https://doi.org/10.3390/catal8120617
Publication status	Published - Dec 2018

Keywords

Heterogeneous catalysis
MCM-41
Mesoporous silica
Molecular sieves
Nanoparticles

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10.3390/catal8120617

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title = "Functionalized ordered mesoporous silicas (MCM-41): Synthesis and applications in catalysis",

abstract = "Mesoporous silica sieves are among the most studied nano-objects due to their stable pore structure and easy preparation. In particular, MCM-41 have attracted increasing research attention due to their chemical versatility. This review focuses on the synthesis and regioselective functionalization of MCM-41 to prepare catalytic systems. The topics covered are: mono and di-functionalized MCM-41 as basic and acid catalysts, catalysts based on metallic complexes and heteropolyacids supported onto MCM-41, metallic nanoparticles embed onto functionalized MCM-41 and magnetic MCM-41 for catalytic purposes.",

keywords = "Heterogeneous catalysis, MCM-41, Mesoporous silica, Molecular sieves, Nanoparticles",

author = "Gabriel Mart{\'i}nez-Edo and Alba Balmori and \{Pont{\'o}n Baroso\}, Iris and \{Del Rio\}, \{Andrea Mart{\'i}\} and \{S{\'a}nchez Garc{\'i}a\}, David",

note = "Publisher Copyright: {\textcopyright} 2018 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2018",

month = dec,

doi = "10.3390/catal8120617",

language = "English",

volume = "8",

journal = "Catalysts",

issn = "2073-4344",

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T1 - Functionalized ordered mesoporous silicas (MCM-41)

T2 - Synthesis and applications in catalysis

AU - Martínez-Edo, Gabriel

AU - Balmori, Alba

AU - Pontón Baroso, Iris

AU - Del Rio, Andrea Martí

AU - Sánchez García, David

PY - 2018/12

Y1 - 2018/12

N2 - Mesoporous silica sieves are among the most studied nano-objects due to their stable pore structure and easy preparation. In particular, MCM-41 have attracted increasing research attention due to their chemical versatility. This review focuses on the synthesis and regioselective functionalization of MCM-41 to prepare catalytic systems. The topics covered are: mono and di-functionalized MCM-41 as basic and acid catalysts, catalysts based on metallic complexes and heteropolyacids supported onto MCM-41, metallic nanoparticles embed onto functionalized MCM-41 and magnetic MCM-41 for catalytic purposes.

AB - Mesoporous silica sieves are among the most studied nano-objects due to their stable pore structure and easy preparation. In particular, MCM-41 have attracted increasing research attention due to their chemical versatility. This review focuses on the synthesis and regioselective functionalization of MCM-41 to prepare catalytic systems. The topics covered are: mono and di-functionalized MCM-41 as basic and acid catalysts, catalysts based on metallic complexes and heteropolyacids supported onto MCM-41, metallic nanoparticles embed onto functionalized MCM-41 and magnetic MCM-41 for catalytic purposes.

KW - Heterogeneous catalysis

KW - MCM-41

KW - Mesoporous silica

KW - Molecular sieves

KW - Nanoparticles

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Functionalized ordered mesoporous silicas (MCM-41): Synthesis and applications in catalysis

Abstract

Keywords

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