Functionalized 2,2’-bipyrroles: Building blocks for Pyrrolic macrocycles

Gonzalo Anguera; James T. Brewster; David Sánchez-García; Jonathan L. Sessler

doi:10.6060/mhc180483s

Functionalized 2,2’-bipyrroles: Building blocks for Pyrrolic macrocycles

Gonzalo Anguera
, James T. Brewster
, David Sánchez-García
, Jonathan L. Sessler^*

^*Corresponding author for this work

Research output: Indexed journal article › Review › peer-review

6 Citations (Scopus)

Abstract

Functionalized N-unsubstituted 2,2’-bipyrroles are basic building blocks for the preparation of pyrrolic macrocycles and natural products, such as prodigiosines. The aim of this review is to provide a description of the most important methodologies used to prepare 2,2’-bipyrroles and their central role as building blocks for the synthesis of porphyrinoids and property-defining structural elements therein.

Original language	English
Pages (from-to)	227-245
Number of pages	19
Journal	Macroheterocycles
Volume	11
Issue number	3
DOIs	https://doi.org/10.6060/mhc180483s
Publication status	Published - 2018

Keywords

2,2’-bipyrroles
Expanded porphyrins
Macrocycles
Oligopyrroles

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10.6060/mhc180483s

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title = "Functionalized 2,2{\textquoteright}-bipyrroles: Building blocks for Pyrrolic macrocycles",

abstract = "Functionalized N-unsubstituted 2,2{\textquoteright}-bipyrroles are basic building blocks for the preparation of pyrrolic macrocycles and natural products, such as prodigiosines. The aim of this review is to provide a description of the most important methodologies used to prepare 2,2{\textquoteright}-bipyrroles and their central role as building blocks for the synthesis of porphyrinoids and property-defining structural elements therein.",

keywords = "2,2{\textquoteright}-bipyrroles, Expanded porphyrins, Macrocycles, Oligopyrroles",

author = "Gonzalo Anguera and Brewster, \{James T.\} and David S{\'a}nchez-Garc{\'i}a and Sessler, \{Jonathan L.\}",

note = "Funding Information: G.A. would like to thank Fundaci{\'o}n Ram{\'o}n Areces for a postdoctoral fellowship. The work in Austin was supported by the National Institutes of Health (CA 686582 to J.L.S.) and the Robert A. Welch Foundation (F-0018 to J.L.S.). J.T.B. would like to thank Axel Stein-br{\"u}ck (UT Austin) for translating the paper by Grabowski and Marchlewski from German to English. Publisher Copyright: {\textcopyright} ISUCT Publishing.",

year = "2018",

doi = "10.6060/mhc180483s",

language = "English",

volume = "11",

pages = "227--245",

journal = "Macroheterocycles",

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T2 - Building blocks for Pyrrolic macrocycles

AU - Anguera, Gonzalo

AU - Brewster, James T.

AU - Sánchez-García, David

AU - Sessler, Jonathan L.

N1 - Funding Information: G.A. would like to thank Fundación Ramón Areces for a postdoctoral fellowship. The work in Austin was supported by the National Institutes of Health (CA 686582 to J.L.S.) and the Robert A. Welch Foundation (F-0018 to J.L.S.). J.T.B. would like to thank Axel Stein-brück (UT Austin) for translating the paper by Grabowski and Marchlewski from German to English. Publisher Copyright: © ISUCT Publishing.

PY - 2018

Y1 - 2018

N2 - Functionalized N-unsubstituted 2,2’-bipyrroles are basic building blocks for the preparation of pyrrolic macrocycles and natural products, such as prodigiosines. The aim of this review is to provide a description of the most important methodologies used to prepare 2,2’-bipyrroles and their central role as building blocks for the synthesis of porphyrinoids and property-defining structural elements therein.

AB - Functionalized N-unsubstituted 2,2’-bipyrroles are basic building blocks for the preparation of pyrrolic macrocycles and natural products, such as prodigiosines. The aim of this review is to provide a description of the most important methodologies used to prepare 2,2’-bipyrroles and their central role as building blocks for the synthesis of porphyrinoids and property-defining structural elements therein.

KW - 2,2’-bipyrroles

KW - Expanded porphyrins

KW - Macrocycles

KW - Oligopyrroles

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ER -

Functionalized 2,2’-bipyrroles: Building blocks for Pyrrolic macrocycles

Abstract

Keywords

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