Fast isomerizing methyl iodide azopyridinium salts for molecular switches

Jaume Garcia-Amorós, Walter A. Massad, Santi Nonell, Dolores Velasco

Research output: Indexed journal article Articlepeer-review

33 Citations (Scopus)

Abstract

(Equation Presented). The usefulness of azopyridinium methyl iodide salts for designing new promising light-controlled molecular switches is presented. Large absorbance changes have been produced in the samples by irradiation with light at λ = 355 nm. The thermal recovery of the initial state took place completely within 130-450 ms, which is much faster than that reported previously for other push-pull azobenzene-doped nematic mixtures.

Original languageEnglish
Pages (from-to)3514-3517
Number of pages4
JournalOrganic Letters
Volume12
Issue number15
Early online date14 Jul 2010
DOIs
Publication statusPublished - 6 Aug 2010

Keywords

  • Photochemical phase-transition
  • Liquid-crystals
  • Azobenzene
  • Behavior

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