Evidence for an 1,7-o,o'-intramolecular Acyl Migration

P VICTORY; JI BORRELL; X Batllori; J TEIXIDO; P CIVIT; A ALVAREZLARENA

doi:10.1246/cl.1993.705

Evidence for an 1,7-o,o'-intramolecular Acyl Migration

P VICTORY
, JI BORRELL
, X Batllori
, J TEIXIDO
, P CIVIT
, A ALVAREZLARENA

IQS

Research output: Indexed journal article › Article › peer-review

3 Citations (Web of Science)

Abstract

The intramolecular nature of the 1,7-O,O'-acyl migration observed during the column chromatography of the diazonium coupling products of methyl 3-acetoxy-6-hydroxy-2-methoxypentafulvene-1-carboxylate was determined by isotopic labeling and mass spectrometry. A cooperative transportation by the hydrazono group is proposed to explain this fact.

Original language	English
Pages (from-to)	705-708
Number of pages	4
Journal	Chemistry Letters
Issue number	4
DOIs	https://doi.org/10.1246/cl.1993.705
Publication status	Published - Apr 1993

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10.1246/cl.1993.705

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abstract = "The intramolecular nature of the 1,7-O,O'-acyl migration observed during the column chromatography of the diazonium coupling products of methyl 3-acetoxy-6-hydroxy-2-methoxypentafulvene-1-carboxylate was determined by isotopic labeling and mass spectrometry. A cooperative transportation by the hydrazono group is proposed to explain this fact.",

author = "P VICTORY and JI BORRELL and X Batllori and J TEIXIDO and P CIVIT and A ALVAREZLARENA",

year = "1993",

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AU - CIVIT, P

AU - ALVAREZLARENA, A

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AB - The intramolecular nature of the 1,7-O,O'-acyl migration observed during the column chromatography of the diazonium coupling products of methyl 3-acetoxy-6-hydroxy-2-methoxypentafulvene-1-carboxylate was determined by isotopic labeling and mass spectrometry. A cooperative transportation by the hydrazono group is proposed to explain this fact.

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Evidence for an 1,7-o,o'-intramolecular Acyl Migration

Abstract

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