Effects of some mineral matrices on flash pyrolysis-GC of soil humic substances

J. Alcañiz; J. Romera; L. Comellas; R. Munne; A. Puigbo

doi:10.1016/0048-9697(89)90113-7

Effects of some mineral matrices on flash pyrolysis-GC of soil humic substances

J. Alcañiz^*
, J. Romera
, L. Comellas
, R. Munne
, A. Puigbo

^*Corresponding author for this work

Research output: Indexed journal article › Article › peer-review

14 Citations (Scopus)

Abstract

The whole soil samples and the humic and fulvic acids extracted from an acid soil (Typic Dystrochrept) were mixed with calcium carbonate,calcium sulfate, silica, alumina, iron-oxide, and then subjected to pyrolysis-gas chromatography. The relative area of the 41 peaks of each pyrogram was compared and numerical parameters were used to analyse the influence of the mineral components on the pyrolytic decomposition. Calcium salts have very little or non-significant effects on soil pyrograms. Amorphous silica, alumina and iron-oxide greatly change the pyrogram pattern. The most evident effect consists of a reduction of the more polar and/or high retention time components.

Original language	English
Pages (from-to)	81-90
Number of pages	10
Journal	Science of the Total Environment
Volume	81-82
Issue number	C
DOIs	https://doi.org/10.1016/0048-9697(89)90113-7
Publication status	Published - Jun 1989

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title = "Effects of some mineral matrices on flash pyrolysis-GC of soil humic substances",

abstract = "The whole soil samples and the humic and fulvic acids extracted from an acid soil (Typic Dystrochrept) were mixed with calcium carbonate,calcium sulfate, silica, alumina, iron-oxide, and then subjected to pyrolysis-gas chromatography. The relative area of the 41 peaks of each pyrogram was compared and numerical parameters were used to analyse the influence of the mineral components on the pyrolytic decomposition. Calcium salts have very little or non-significant effects on soil pyrograms. Amorphous silica, alumina and iron-oxide greatly change the pyrogram pattern. The most evident effect consists of a reduction of the more polar and/or high retention time components.",

author = "J. Alca{\~n}iz and J. Romera and L. Comellas and R. Munne and A. Puigbo",

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AU - Alcañiz, J.

AU - Romera, J.

AU - Comellas, L.

AU - Munne, R.

AU - Puigbo, A.

PY - 1989/6

Y1 - 1989/6

N2 - The whole soil samples and the humic and fulvic acids extracted from an acid soil (Typic Dystrochrept) were mixed with calcium carbonate,calcium sulfate, silica, alumina, iron-oxide, and then subjected to pyrolysis-gas chromatography. The relative area of the 41 peaks of each pyrogram was compared and numerical parameters were used to analyse the influence of the mineral components on the pyrolytic decomposition. Calcium salts have very little or non-significant effects on soil pyrograms. Amorphous silica, alumina and iron-oxide greatly change the pyrogram pattern. The most evident effect consists of a reduction of the more polar and/or high retention time components.

AB - The whole soil samples and the humic and fulvic acids extracted from an acid soil (Typic Dystrochrept) were mixed with calcium carbonate,calcium sulfate, silica, alumina, iron-oxide, and then subjected to pyrolysis-gas chromatography. The relative area of the 41 peaks of each pyrogram was compared and numerical parameters were used to analyse the influence of the mineral components on the pyrolytic decomposition. Calcium salts have very little or non-significant effects on soil pyrograms. Amorphous silica, alumina and iron-oxide greatly change the pyrogram pattern. The most evident effect consists of a reduction of the more polar and/or high retention time components.

UR - https://www.scopus.com/pages/publications/0024568286

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VL - 81-82

SP - 81

EP - 90

JO - Science of the Total Environment

JF - Science of the Total Environment

IS - C

ER -

Effects of some mineral matrices on flash pyrolysis-GC of soil humic substances

Abstract

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