A hexaco-ordinate platinum complex containing four Pt-Sn bonds, one of them to SnII

Joaquim F. Almeida; Keith R. Dixon; Colin Eaborn; Peter B. Hitchcock; Alan Pidcock; J. Vinaixa Serra

doi:10.1039/C39820001315

A hexaco-ordinate platinum complex containing four Pt-Sn bonds, one of them to Sn^II

Joaquim F. Almeida
, Keith R. Dixon
, Colin Eaborn
, Peter B. Hitchcock
, Alan Pidcock^*
, J. Vinaixa Serra

^*Corresponding author for this work

Research output: Indexed journal article › Article › peer-review

29 Citations (Scopus)

Abstract

The complex [Pt(CO₃)(SEt₂)(PEt₃)] reacts readily with SnR₃H (R = p-MeC₆H₄) in MeOH to give a hexaco-ordinate Pt^IV complex in which the ligands are PEt ₃, H (these two being trans to one another), R₃Sn ^IV, R₂Sn^II, and 2 × R₂(MeO) Sn^IV, with the OMe groups of the last ligands bridging to the R ₂Sn^II centre; the four Sn and two O atoms lie approximately in a plane, with the Pt atom 0.48 Å out of this plane towards the PEt₃ ligand.

Original language	English
Pages (from-to)	1315-1316
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39820001315
Publication status	Published - 1982
Externally published	Yes

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@article{e3de3540275c4851bc8224d9212709ff,

title = "A hexaco-ordinate platinum complex containing four Pt-Sn bonds, one of them to SnII",

abstract = "The complex [Pt(CO3)(SEt2)(PEt3)] reacts readily with SnR3H (R = p-MeC6H4) in MeOH to give a hexaco-ordinate PtIV complex in which the ligands are PEt 3, H (these two being trans to one another), R3Sn IV, R2SnII, and 2 {\texttimes} R2(MeO) SnIV, with the OMe groups of the last ligands bridging to the R 2SnII centre; the four Sn and two O atoms lie approximately in a plane, with the Pt atom 0.48 {\AA} out of this plane towards the PEt3 ligand.",

author = "Almeida, \{Joaquim F.\} and Dixon, \{Keith R.\} and Colin Eaborn and Hitchcock, \{Peter B.\} and Alan Pidcock and \{Vinaixa Serra\}, J.",

note = "Funding Information: We thank the S.E.R.C. for partial support of this work (viaC.E.), the University of Victoria for study leave funding (K.R.D.), the Caixa de Barcelona for a research fellowship (J.V.), and the Instituto Nacional de Investigaqiio Cientifica (Portugal) for financial support (J.F.A.). Received, 4th Scptemher I982; Corn. 1064 References 1 C. Eaborn, A. Pidcock, and B. R. Steele, J. Chern. Soc., Ddtun Tran.v., 1975, 809; J. F. Almeida, H. Aziiian, C. Eaborn, and A. Pidcock, J. Organornet. Chem., 1981, 210, 121. 2 C. Eaborn, K. Kundu, and A. Pidcock, J. Chem. Soc., Dalton Trans., 1981, 1223, and references therein; T. A. K. Al-Allaf, C. Eaborn, K. Kundu, and A. Pidcock, J. Chem Soc., Ckem. Commun., 1981, 55.",

year = "1982",

doi = "10.1039/C39820001315",

language = "English",

pages = "1315--1316",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "22",

}

TY - JOUR

T1 - A hexaco-ordinate platinum complex containing four Pt-Sn bonds, one of them to SnII

AU - Almeida, Joaquim F.

AU - Dixon, Keith R.

AU - Eaborn, Colin

AU - Hitchcock, Peter B.

AU - Pidcock, Alan

AU - Vinaixa Serra, J.

N1 - Funding Information: We thank the S.E.R.C. for partial support of this work (viaC.E.), the University of Victoria for study leave funding (K.R.D.), the Caixa de Barcelona for a research fellowship (J.V.), and the Instituto Nacional de Investigaqiio Cientifica (Portugal) for financial support (J.F.A.). Received, 4th Scptemher I982; Corn. 1064 References 1 C. Eaborn, A. Pidcock, and B. R. Steele, J. Chern. Soc., Ddtun Tran.v., 1975, 809; J. F. Almeida, H. Aziiian, C. Eaborn, and A. Pidcock, J. Organornet. Chem., 1981, 210, 121. 2 C. Eaborn, K. Kundu, and A. Pidcock, J. Chem. Soc., Dalton Trans., 1981, 1223, and references therein; T. A. K. Al-Allaf, C. Eaborn, K. Kundu, and A. Pidcock, J. Chem Soc., Ckem. Commun., 1981, 55.

PY - 1982

Y1 - 1982

N2 - The complex [Pt(CO3)(SEt2)(PEt3)] reacts readily with SnR3H (R = p-MeC6H4) in MeOH to give a hexaco-ordinate PtIV complex in which the ligands are PEt 3, H (these two being trans to one another), R3Sn IV, R2SnII, and 2 × R2(MeO) SnIV, with the OMe groups of the last ligands bridging to the R 2SnII centre; the four Sn and two O atoms lie approximately in a plane, with the Pt atom 0.48 Å out of this plane towards the PEt3 ligand.

AB - The complex [Pt(CO3)(SEt2)(PEt3)] reacts readily with SnR3H (R = p-MeC6H4) in MeOH to give a hexaco-ordinate PtIV complex in which the ligands are PEt 3, H (these two being trans to one another), R3Sn IV, R2SnII, and 2 × R2(MeO) SnIV, with the OMe groups of the last ligands bridging to the R 2SnII centre; the four Sn and two O atoms lie approximately in a plane, with the Pt atom 0.48 Å out of this plane towards the PEt3 ligand.

UR - https://www.scopus.com/pages/publications/37049110665

U2 - 10.1039/C39820001315

DO - 10.1039/C39820001315

M3 - Article

AN - SCOPUS:37049110665

SN - 0022-4936

SP - 1315

EP - 1316

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 22

ER -

A hexaco-ordinate platinum complex containing four Pt-Sn bonds, one of them to Sn^II

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