Transition-metal-free B-B and B-interelement reactions with organic molecules

Ana B. Cuenca, Ryosuke Shishido, Hajime Ito, Elena Fernández

Producció científica: Article en revista indexadaArticle de revisió (sistemàtica)Avaluat per experts

263 Cites (Scopus)

Resum

This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of B-B and B-interelement bonds, as well as the generation of new C-B and C-interelement bonds, in a selective way. The greener consequences of these novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidence that supports the innovative theories are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field.

Idioma originalAnglès
Pàgines (de-a)415-430
Nombre de pàgines16
RevistaChemical Society Reviews
Volum46
Número2
DOIs
Estat de la publicacióPublicada - 21 de gen. 2017

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