Synthesis, photophysical studies and 1O2 generation of carboxylate-terminated zinc phthalocyanine dendrimers

Francesca Setaro, Rubén Ruiz-González, Santi Nonell, Uwe Hahn, Tomás Torres

Producció científica: Article en revista indexadaArticleAvaluat per experts

32 Cites (Scopus)

Resum

Highly water-soluble dendrimers have been prepared consisting of a central zinc phthalocyanine moiety and dendritic wedges with terminal carboxylate groups. The biggest polyelectrolyte comprises 32 negative charges at the dendrimer surface. The photophysical studies reveal a strong correlation between the degree of dendritic environment, the extent of aggregation, and the ability to generate singlet oxygen in aqueous media. Compared to dendrimers having an axial derivatization the functionalization on the outer rim also significantly improves the phthalocyanine's ability to photosensitize singlet oxygen.

Idioma originalAnglès
Pàgines (de-a)170-176
Nombre de pàgines7
RevistaJournal of Inorganic Biochemistry
Volum136
DOIs
Estat de la publicacióPublicada - de jul. 2014

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