Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster; Qing He; Gonzalo Anguera; Matthew D. Moore; Xian Sheng Ke; Vincent M. Lynch; Jonathan L. Sessler

doi:10.1039/c7cc01674c

Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster, Qing He, Gonzalo Anguera, Matthew D. Moore, Xian Sheng Ke, Vincent M. Lynch, Jonathan L. Sessler^*

^*Autor corresponent d’aquest treball

Producció científica: Article en revista indexada › Article › Avaluat per experts

32 Cites (Scopus)

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The reaction between non-aqueous uranyl silylamide (UO₂[N(SiMe₃)₂]₂·2THF) under anaerobic conditions or uranyl acetate (UO₂(OAc)₂·2H₂O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

Idioma original	Anglès
Pàgines (de-a)	4981-4984
Nombre de pàgines	4
Revista	Chemical Communications
Volum	53
Número	36
DOIs	https://doi.org/10.1039/c7cc01674c
Estat de la publicació	Publicada - 2017
Publicat externament	Sí

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title = "Synthesis and characterization of a dipyriamethyrin-uranyl complex",

abstract = "The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.",

author = "Brewster, {James T.} and Qing He and Gonzalo Anguera and Moore, {Matthew D.} and Ke, {Xian Sheng} and Lynch, {Vincent M.} and Sessler, {Jonathan L.}",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7cc01674c",

language = "English",

volume = "53",

pages = "4981--4984",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Synthesis and characterization of a dipyriamethyrin-uranyl complex

AU - Brewster, James T.

AU - He, Qing

AU - Anguera, Gonzalo

AU - Moore, Matthew D.

AU - Ke, Xian Sheng

AU - Lynch, Vincent M.

AU - Sessler, Jonathan L.

PY - 2017

Y1 - 2017

N2 - The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

AB - The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

UR - http://www.scopus.com/inward/record.url?scp=85021661440&partnerID=8YFLogxK

U2 - 10.1039/c7cc01674c

DO - 10.1039/c7cc01674c

M3 - Article

C2 - 28425551

AN - SCOPUS:85021661440

SN - 1359-7345

VL - 53

SP - 4981

EP - 4984

JO - Chemical Communications

JF - Chemical Communications

IS - 36

ER -

Synthesis and characterization of a dipyriamethyrin-uranyl complex

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