Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster, Qing He, Gonzalo Anguera, Matthew D. Moore, Xian Sheng Ke, Vincent M. Lynch, Jonathan L. Sessler

Producció científica: Article en revista indexadaArticleAvaluat per experts

28 Cites (Scopus)

Resum

The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

Idioma originalAnglès
Pàgines (de-a)4981-4984
Nombre de pàgines4
RevistaChemical Communications
Volum53
Número36
DOIs
Estat de la publicacióPublicada - 2017
Publicat externament

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