@article{69dc1c57e7af4678a85d8e4753570fcf,
title = "Strategic Trimethylsilyldiazomethane Insertion into pinB-SR Followed by Selective Alkylations",
abstract = "The insertion of the diazo derivative Me3SiCHN2 into pinB-SR σ bonds (R = Ph, Tol, Bn) allows a direct synthesis of multisubstituted H-C(SR)(Bpin)(SiMe3) compounds. Consecutive base-assisted transformations of HC(S)(B) (Si) systems lead to deborylative alkylations, Sommelet-Ha{\"u}ser rearrangements, and deprotoalkylations. Intramolecular cyclizations can be selectively performed either via desilylative or deborylative manifolds by fine-tuning the base employed.",
keywords = "Addition-reactions, Boronic esters, Alkyl-halides, Carbanions, Deprotonation, Homologation, Diborylation, Derivatives, Alcohols, Boranes",
author = "Civit, {Marc G.} and Jordi Royes and Vogels, {Christopher M.} and Westcott, {Stephen A.} and Cuenca, {Ana B.} and Elena Fern{\'a}ndez",
note = "Funding Information: The present research was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) through Project No. CTQ2013-43395P (EF) and by NSERC (SAW) Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",
year = "2016",
month = aug,
day = "5",
doi = "10.1021/acs.orglett.6b01840",
language = "English",
volume = "18",
pages = "3830--3833",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "15",
}