Regiospecific base-catalysed pinacol-type rearrangement of cyclic α-hydroxy toluenesulfonates: Ring Contraction vs. alkyl migration in sesquiterpene derivatives

Antoni Planas; Manuel Cortés; Juan Julio Bonet

Regiospecific base-catalysed pinacol-type rearrangement of cyclic α-hydroxy toluenesulfonates: Ring Contraction vs. alkyl migration in sesquiterpene derivatives

Antoni Planas
, Manuel Cortés
, Juan Julio Bonet

IQS

Producció científica: Article en revista indexada › Article › Avaluat per experts

1 Citació (Web of Science)

Resum

La reacció de α-hidroxitoluensulfonats sesquiterpènics amb hidrur de liti i alumini dóna lloc a compostos que provenen d'una contracció d'anell o d'una emigració d'un reste alquil, segons l'estereoquímica dels productes de partença.

Idioma original	Anglès
Pàgines (de-a)	375-376
Nombre de pàgines	2
Revista	Afinidad
Volum	42
Número	398
Estat de la publicació	Publicada - d’ag. 1985

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@article{93ba699b503e464c9dbc61680dbc8b08,

title = "Regiospecific base-catalysed pinacol-type rearrangement of cyclic α-hydroxy toluenesulfonates: Ring Contraction vs. alkyl migration in sesquiterpene derivatives",

abstract = "Reaction of sesquiterpenic α-hydroxy toluenesulfonates with lithium aluminium hydride gives compounds resulting from ring contraction or alkyl migration, depending on the stereochemistry of the starting products.",

author = "Antoni Planas and Manuel Cort{\'e}s and Bonet, \{Juan Julio\}",

year = "1985",

month = aug,

language = "English",

volume = "42",

pages = "375--376",

journal = "Afinidad",

issn = "0001-9704",

publisher = "Asociacion de Quimicos del Instituto Quimico de Sarria",

number = "398",

}

TY - JOUR

T1 - Regiospecific base-catalysed pinacol-type rearrangement of cyclic α-hydroxy toluenesulfonates

T2 - Ring Contraction vs. alkyl migration in sesquiterpene derivatives

AU - Planas, Antoni

AU - Cortés, Manuel

AU - Bonet, Juan Julio

PY - 1985/8

Y1 - 1985/8

N2 - Reaction of sesquiterpenic α-hydroxy toluenesulfonates with lithium aluminium hydride gives compounds resulting from ring contraction or alkyl migration, depending on the stereochemistry of the starting products.

AB - Reaction of sesquiterpenic α-hydroxy toluenesulfonates with lithium aluminium hydride gives compounds resulting from ring contraction or alkyl migration, depending on the stereochemistry of the starting products.

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=pure_univeritat_ramon_llull&SrcAuth=WosAPI&KeyUT=WOS:A1985ASN1700006&DestLinkType=FullRecord&DestApp=WOS

M3 - Article

SN - 0001-9704

VL - 42

SP - 375

EP - 376

JO - Afinidad

JF - Afinidad

IS - 398

ER -

Regiospecific base-catalysed pinacol-type rearrangement of cyclic α-hydroxy toluenesulfonates: Ring Contraction vs. alkyl migration in sesquiterpene derivatives

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