Organocatalytic functionalisation through boron chemistry

Gerard Palau-Lluch; Xavier Sanz; Enrico La Cascia; Marc G. Civit; Nuria Miralles; Ana B. Cuenca; Elena Fernández

doi:10.1515/pac-2014-0934

Organocatalytic functionalisation through boron chemistry

Gerard Palau-Lluch, Xavier Sanz, Enrico La Cascia, Marc G. Civit, Nuria Miralles, Ana B. Cuenca, Elena Fernández

Producció científica: Article en revista indexada › Article › Avaluat per experts

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Resum

Diboron reagents can be activated both, from a metal or free-metal context, and consequently the addition of boryl units to unsaturated substrates proceeds sometimes with complementary selectivity. We highlight here the power of boron chemistry to functionalize molecules and provide new routes towards challenging compounds.

Idioma original	Anglès
Pàgines (de-a)	181-193
Nombre de pàgines	13
Revista	Pure and Applied Chemistry
Volum	87
Número	2
DOIs	https://doi.org/10.1515/pac-2014-0934
Estat de la publicació	Publicada - 1 de febr. 2015
Publicat externament	Sí
Esdeveniment	15th International Conference on Boron Chemistry (IMEBORON) - Prague, Czech Republic Durada: 24 d’ag. 2014 → 28 d’ag. 2014

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title = "Organocatalytic functionalisation through boron chemistry",

abstract = "Diboron reagents can be activated both, from a metal or free-metal context, and consequently the addition of boryl units to unsaturated substrates proceeds sometimes with complementary selectivity. We highlight here the power of boron chemistry to functionalize molecules and provide new routes towards challenging compounds.",

keywords = "Boranes, Enantioselectivity, IMEBORON XV, Nucleophilic addition",

author = "Gerard Palau-Lluch and Xavier Sanz and {La Cascia}, Enrico and Civit, {Marc G.} and Nuria Miralles and Cuenca, {Ana B.} and Elena Fern{\'a}ndez",

note = "Publisher Copyright: {\textcopyright} 2014 IUPAC & De Gruyter.; 15th International Conference on Boron Chemistry (IMEBORON) ; Conference date: 24-08-2014 Through 28-08-2014",

year = "2015",

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doi = "10.1515/pac-2014-0934",

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T1 - Organocatalytic functionalisation through boron chemistry

AU - Palau-Lluch, Gerard

AU - Sanz, Xavier

AU - La Cascia, Enrico

AU - Civit, Marc G.

AU - Miralles, Nuria

AU - Cuenca, Ana B.

AU - Fernández, Elena

PY - 2015/2/1

Y1 - 2015/2/1

N2 - Diboron reagents can be activated both, from a metal or free-metal context, and consequently the addition of boryl units to unsaturated substrates proceeds sometimes with complementary selectivity. We highlight here the power of boron chemistry to functionalize molecules and provide new routes towards challenging compounds.

AB - Diboron reagents can be activated both, from a metal or free-metal context, and consequently the addition of boryl units to unsaturated substrates proceeds sometimes with complementary selectivity. We highlight here the power of boron chemistry to functionalize molecules and provide new routes towards challenging compounds.

KW - Boranes

KW - Enantioselectivity

KW - IMEBORON XV

KW - Nucleophilic addition

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VL - 87

SP - 181

EP - 193

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

IS - 2

T2 - 15th International Conference on Boron Chemistry (IMEBORON)

Y2 - 24 August 2014 through 28 August 2014

ER -

Organocatalytic functionalisation through boron chemistry

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