Opportune gem-Silylborylation of Carbonyl Compounds: A Modular and Stereocontrolled Entry to Tetrasubstituted Olefins

Enrico La Cascia, Ana B. Cuenca, Elena Fernández

Producció científica: Article en revista indexadaArticleAvaluat per experts

47 Cites (Scopus)

Resum

An easy access to highly versatile gem-silylboronate synthons is achieved by means of a new olefination reagent, HC(Bpin)2(SiMe3). Subsequent silicon or boron-based selective functionalization allows for the modular and stereocontrolled synthesis of all-carbon tetrasubstituted alkenes. A particular attraction of this approach is the iododesilylation reaction, which becomes a pivotal tool for C−Si functionalization.

Idioma originalAnglès
Pàgines (de-a)18737-18741
Nombre de pàgines5
RevistaChemistry - A European Journal
Volum22
Número52
DOIs
Estat de la publicacióPublicada - 23 de des. 2016
Publicat externament

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