One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes

David Sánchez-García; José I. Borrell; Santi Nonell

doi:10.1021/ol802380g

One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes

David Sánchez-García, José I. Borrell, Santi Nonell

Producció científica: Article en revista indexada › Article › Avaluat per experts

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Resum

A one-pot reaction for the synthesis of 4,4'-diaryl-and 4,4'-diheteroaryl-substituted 2,2'-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2'-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.

Idioma original	Anglès
Pàgines (de-a)	77-79
Nombre de pàgines	3
Revista	Organic Letters
Volum	11
Número	1
DOIs	https://doi.org/10.1021/ol802380g
Estat de la publicació	Publicada - 1 de gen. 2009

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abstract = "A one-pot reaction for the synthesis of 4,4'-diaryl-and 4,4'-diheteroaryl-substituted 2,2'-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2'-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.",

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author = "David S{\'a}nchez-Garc{\'i}a and Borrell, {Jos{\'e} I.} and Santi Nonell",

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doi = "10.1021/ol802380g",

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T1 - One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes

AU - Sánchez-García, David

AU - Borrell, José I.

AU - Nonell, Santi

PY - 2009/1/1

Y1 - 2009/1/1

N2 - A one-pot reaction for the synthesis of 4,4'-diaryl-and 4,4'-diheteroaryl-substituted 2,2'-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2'-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.

AB - A one-pot reaction for the synthesis of 4,4'-diaryl-and 4,4'-diheteroaryl-substituted 2,2'-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2'-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.

KW - Photodynamic therapy

KW - Chemistry

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One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes

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