Hybrid proton-conducting membranes for polymer electrolyte fuel cells: Phosphomolybdic acid doped poly(2,5-benzimidazole) - (ABPBI-H 3PMo12O40)

Pedro Gómez-Romero; Juan Antonio Asensio; Salvador Borrós

doi:10.1016/j.electacta.2005.02.029

Hybrid proton-conducting membranes for polymer electrolyte fuel cells: Phosphomolybdic acid doped poly(2,5-benzimidazole) - (ABPBI-H ₃PMo₁₂O₄₀)

Pedro Gómez-Romero, Juan Antonio Asensio, Salvador Borrós

Producció científica: Article en revista indexada › Article › Avaluat per experts

81 Cites (Scopus)

Resum

The synthesis and characterization of a novel hybrid organic-inorganic material formed by phosphomolybdic acid H₃PMo₁₂O ₄₀ (PMo₁₂) and poly(2,5-benzimidazole) (ABPBI) is reported. This material, composed of two proton-conducting components, can be cast in the form of membranes from methanesulfonic acid (MSA) solutions. Upon impregnation with phosphoric acid, the hybrid membranes present higher conductivity than the best ABPBI polymer membranes impregnated in the same conditions. These electrolyte membranes are stable up to 200 °C, and have a proton conductivity of 3 × 10^-2 S cm^-1 at 185 °C without humidification. These properties make them very good candidates as membranes for polymer electrolyte membrane fuel cells (PEMFC) at temperatures of 100-200 °C.

Idioma original	Anglès
Pàgines (de-a)	4715-4720
Nombre de pàgines	6
Revista	Electrochimica Acta
Volum	50
Número	24
DOIs	https://doi.org/10.1016/j.electacta.2005.02.029
Estat de la publicació	Publicada - 30 d’ag. 2005

Accés al document

10.1016/j.electacta.2005.02.029

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Com citar-ho

@article{4019a3bb3bbe40c1946de426ca422fbe,

title = "Hybrid proton-conducting membranes for polymer electrolyte fuel cells: Phosphomolybdic acid doped poly(2,5-benzimidazole) - (ABPBI-H 3PMo12O40)",

abstract = "The synthesis and characterization of a novel hybrid organic-inorganic material formed by phosphomolybdic acid H3PMo12O 40 (PMo12) and poly(2,5-benzimidazole) (ABPBI) is reported. This material, composed of two proton-conducting components, can be cast in the form of membranes from methanesulfonic acid (MSA) solutions. Upon impregnation with phosphoric acid, the hybrid membranes present higher conductivity than the best ABPBI polymer membranes impregnated in the same conditions. These electrolyte membranes are stable up to 200 °C, and have a proton conductivity of 3 × 10-2 S cm-1 at 185 °C without humidification. These properties make them very good candidates as membranes for polymer electrolyte membrane fuel cells (PEMFC) at temperatures of 100-200 °C.",

keywords = "ABPBI, Fuel cell membrane, Heteropolyacid, Hybrid materials, PBI, PEM fuel cells, Phosphomolybdic acid, Polybenzimidazole, Polyoxometalate, Proton conductor, Proton exchange membranes",

author = "Pedro G{\'o}mez-Romero and Asensio, {Juan Antonio} and Salvador Borr{\'o}s",

note = "Funding Information: This work was carried out within the framework of the Xarxa Tem{\`a}tica de Piles de Combustible” de la Generalitat de Catalunya, and the “Red de Pilas de Combustible del CSIC” and was partially funded by MCyT (Spain) (MAT2002-04529-C03). We thank the MCyT for a pre-doctoral fellowship awarded to J.A.A.",

year = "2005",

month = aug,

day = "30",

doi = "10.1016/j.electacta.2005.02.029",

language = "English",

volume = "50",

pages = "4715--4720",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Ltd.",

number = "24",

}

Hybrid proton-conducting membranes for polymer electrolyte fuel cells: Phosphomolybdic acid doped poly(2,5-benzimidazole) - (ABPBI-H ₃PMo₁₂O₄₀). / Gómez-Romero, Pedro; Asensio, Juan Antonio; Borrós, Salvador.
In: Electrochimica Acta, Vol. 50, Núm. 24, 30.08.2005, pàg. 4715-4720.

Producció científica: Article en revista indexada › Article › Avaluat per experts

TY - JOUR

T1 - Hybrid proton-conducting membranes for polymer electrolyte fuel cells

T2 - Phosphomolybdic acid doped poly(2,5-benzimidazole) - (ABPBI-H 3PMo12O40)

AU - Gómez-Romero, Pedro

AU - Asensio, Juan Antonio

AU - Borrós, Salvador

N1 - Funding Information: This work was carried out within the framework of the Xarxa Temàtica de Piles de Combustible” de la Generalitat de Catalunya, and the “Red de Pilas de Combustible del CSIC” and was partially funded by MCyT (Spain) (MAT2002-04529-C03). We thank the MCyT for a pre-doctoral fellowship awarded to J.A.A.

PY - 2005/8/30

Y1 - 2005/8/30

N2 - The synthesis and characterization of a novel hybrid organic-inorganic material formed by phosphomolybdic acid H3PMo12O 40 (PMo12) and poly(2,5-benzimidazole) (ABPBI) is reported. This material, composed of two proton-conducting components, can be cast in the form of membranes from methanesulfonic acid (MSA) solutions. Upon impregnation with phosphoric acid, the hybrid membranes present higher conductivity than the best ABPBI polymer membranes impregnated in the same conditions. These electrolyte membranes are stable up to 200 °C, and have a proton conductivity of 3 × 10-2 S cm-1 at 185 °C without humidification. These properties make them very good candidates as membranes for polymer electrolyte membrane fuel cells (PEMFC) at temperatures of 100-200 °C.

AB - The synthesis and characterization of a novel hybrid organic-inorganic material formed by phosphomolybdic acid H3PMo12O 40 (PMo12) and poly(2,5-benzimidazole) (ABPBI) is reported. This material, composed of two proton-conducting components, can be cast in the form of membranes from methanesulfonic acid (MSA) solutions. Upon impregnation with phosphoric acid, the hybrid membranes present higher conductivity than the best ABPBI polymer membranes impregnated in the same conditions. These electrolyte membranes are stable up to 200 °C, and have a proton conductivity of 3 × 10-2 S cm-1 at 185 °C without humidification. These properties make them very good candidates as membranes for polymer electrolyte membrane fuel cells (PEMFC) at temperatures of 100-200 °C.

KW - ABPBI

KW - Fuel cell membrane

KW - Heteropolyacid

KW - Hybrid materials

KW - PBI

KW - PEM fuel cells

KW - Phosphomolybdic acid

KW - Polybenzimidazole

KW - Polyoxometalate

KW - Proton conductor

KW - Proton exchange membranes

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DO - 10.1016/j.electacta.2005.02.029

M3 - Article

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SN - 0013-4686

VL - 50

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EP - 4720

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 24

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