Gram-Scale Synthesis of a Bench-Stable 5,5″-Unsubstituted Terpyrrole

James T. Brewster, Hadiqa Zafar, Matthew McVeigh, Christopher D. Wight, Gonzalo Anguera, Axel Steinbrück, Vincent M. Lynch, Jonathan L. Sessler

Producció científica: Article en revista indexadaArticleAvaluat per experts

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The controlled preparation of higher order oligopyrrolic species holds broad utility across the chemical and material sciences. Here, we describe the gram-scale synthesis of a bench-stable 5,5″-unsubstituted terpyrrole in excellent yield via a tandem Suzuki cross-coupling with in situ deprotection. The solution and solid-state stability as well as UV-vis, fluorescence, and single crystal X-ray diffraction structure are also detailed.

Idioma originalAnglès
Pàgines (de-a)9568-9570
Nombre de pàgines3
RevistaJournal of Organic Chemistry
Estat de la publicacióPublicada - 17 d’ag. 2018
Publicat externament


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