Gold(I)-catalysed cascade reactions in the synthesis of 2,3-fused indole derivatives

Ana Gimeno, Alejandra Rodríguez-Gimeno, Ana B. Cuenca, Carmen Ramírez De Arellano, Mercedes Medio-Simón, Gregorio Asensio

Producció científica: Article en revista indexadaArticleAvaluat per experts

23 Cites (Scopus)

Resum

A gold(I)-catalysed hydroaminative/arylative cascade for the efficient synthesis of a variety of indole-fused skeletons has been developed. Factors controlling the catalyst loading required in these transformations involving 1,3-unsubstituted indole intermediates have been revealed, allowing isolation of an unprecedented 1,3-dimetallated 3H-indole gold complex characterized by X-ray diffraction.

Idioma originalAnglès
Pàgines (de-a)12384-12387
Nombre de pàgines4
RevistaChemical Communications
Volum51
Número62
DOIs
Estat de la publicacióPublicada - 11 d’ag. 2015
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