TY - JOUR
T1 - Functionalized ordered mesoporous silicas (MCM-41)
T2 - Synthesis and applications in catalysis
AU - Martínez-Edo, Gabriel
AU - Balmori, Alba
AU - Pontón, Iris
AU - Del Rio, Andrea Martí
AU - Sánchez-García, David
N1 - Publisher Copyright:
© 2018 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2018/12
Y1 - 2018/12
N2 - Mesoporous silica sieves are among the most studied nano-objects due to their stable pore structure and easy preparation. In particular, MCM-41 have attracted increasing research attention due to their chemical versatility. This review focuses on the synthesis and regioselective functionalization of MCM-41 to prepare catalytic systems. The topics covered are: mono and di-functionalized MCM-41 as basic and acid catalysts, catalysts based on metallic complexes and heteropolyacids supported onto MCM-41, metallic nanoparticles embed onto functionalized MCM-41 and magnetic MCM-41 for catalytic purposes.
AB - Mesoporous silica sieves are among the most studied nano-objects due to their stable pore structure and easy preparation. In particular, MCM-41 have attracted increasing research attention due to their chemical versatility. This review focuses on the synthesis and regioselective functionalization of MCM-41 to prepare catalytic systems. The topics covered are: mono and di-functionalized MCM-41 as basic and acid catalysts, catalysts based on metallic complexes and heteropolyacids supported onto MCM-41, metallic nanoparticles embed onto functionalized MCM-41 and magnetic MCM-41 for catalytic purposes.
KW - Heterogeneous catalysis
KW - MCM-41
KW - Mesoporous silica
KW - Molecular sieves
KW - Nanoparticles
UR - http://www.scopus.com/inward/record.url?scp=85062552616&partnerID=8YFLogxK
UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=pure_univeritat_ramon_llull&SrcAuth=WosAPI&KeyUT=WOS:000454711500049&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.3390/catal8120617
DO - 10.3390/catal8120617
M3 - Review
AN - SCOPUS:85062552616
SN - 2073-4344
VL - 8
JO - Catalysts
JF - Catalysts
IS - 12
M1 - 617
ER -