Combining AlCl3·6H2O and an ionic liquid to prepare chlorohydrin esters from glycerol

Gemma Villorbina, Albert Tomàs, Marc Escribà, Mireia Oromí-Farrús, Jordi Eras, Mercè Balcells, Ramon Canela

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14 Cites (Scopus)

Resum

We describe here the first example in which glycerol has been transformed into chlorohydrin esters using an ionic liquid and hydrated aluminium chloride. The method avoids using Crown-18 ether, which was needed to obtain a similar yield when KCl was used. Alkyl and aryl acids can be used, although yields are very dependent on the carboxylic acid used.

Idioma originalAnglès
Pàgines (de-a)2828-2830
Nombre de pàgines3
RevistaTetrahedron Letters
Volum50
Número23
DOIs
Estat de la publicacióPublicada - 10 de juny 2009
Publicat externament

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