Aplicación del método NPK a la determinación de la cinética de descomposición del triperóxido de triciclohexilideno

J. Sempere; R. Nomen; E. Serra; D. De Armas

Aplicación del método NPK a la determinación de la cinética de descomposición del triperóxido de triciclohexilideno

J. Sempere^*, R. Nomen, E. Serra, D. De Armas

^*Autor corresponent d’aquest treball

Producció científica: Article en revista indexada › Article › Avaluat per experts

4 Cites (Scopus)

Resum

The process of thermal decomposition of tricyclohexylidene triperoxide in n-dodecane solution is studied using differential scanning calorimetry -DSC-. Kinetic analysis of data is performed using the non-parametric kinetics method -NPK-, not requiring any theoretical model and allowing the simulation of the behaviour of the process. Activation energy has a value of 1.5 · 10 ⁵ J · mol^-1 and a JMA model -Johnson, Mehl and Avrami- fits the data giving an indication of the type of process.

Títol traduït de la contribució	Kinetic analysis of the thermal decomposition of tricyclohexylidene triperoxide using the NPK method
Idioma original	Castellà
Pàgines (de-a)	520-524
Nombre de pàgines	5
Revista	Afinidad
Volum	62
Número	519
Estat de la publicació	Publicada - de set. 2005

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@article{f721e3b33c9b48128e86c461c009ad5a,

title = "Aplicaci{\'o}n del m{\'e}todo NPK a la determinaci{\'o}n de la cin{\'e}tica de descomposici{\'o}n del triper{\'o}xido de triciclohexilideno",

abstract = "The process of thermal decomposition of tricyclohexylidene triperoxide in n-dodecane solution is studied using differential scanning calorimetry -DSC-. Kinetic analysis of data is performed using the non-parametric kinetics method -NPK-, not requiring any theoretical model and allowing the simulation of the behaviour of the process. Activation energy has a value of 1.5 · 10 5 J · mol-1 and a JMA model -Johnson, Mehl and Avrami- fits the data giving an indication of the type of process.",

keywords = "DSC, Differential scanning calorimetry, Kinetic analysis, NPK, Non-Parametric Kinetics, Thermal decomposition",

author = "J. Sempere and R. Nomen and E. Serra and {De Armas}, D.",

year = "2005",

month = sep,

language = "Espa{\~n}ol",

volume = "62",

pages = "520--524",

journal = "Afinidad",

issn = "0001-9704",

publisher = "Asociacion de Quimicos del Instituto Quimico de Sarria",

number = "519",

}

TY - JOUR

T1 - Aplicación del método NPK a la determinación de la cinética de descomposición del triperóxido de triciclohexilideno

AU - Sempere, J.

AU - Nomen, R.

AU - Serra, E.

AU - De Armas, D.

PY - 2005/9

Y1 - 2005/9

N2 - The process of thermal decomposition of tricyclohexylidene triperoxide in n-dodecane solution is studied using differential scanning calorimetry -DSC-. Kinetic analysis of data is performed using the non-parametric kinetics method -NPK-, not requiring any theoretical model and allowing the simulation of the behaviour of the process. Activation energy has a value of 1.5 · 10 5 J · mol-1 and a JMA model -Johnson, Mehl and Avrami- fits the data giving an indication of the type of process.

AB - The process of thermal decomposition of tricyclohexylidene triperoxide in n-dodecane solution is studied using differential scanning calorimetry -DSC-. Kinetic analysis of data is performed using the non-parametric kinetics method -NPK-, not requiring any theoretical model and allowing the simulation of the behaviour of the process. Activation energy has a value of 1.5 · 10 5 J · mol-1 and a JMA model -Johnson, Mehl and Avrami- fits the data giving an indication of the type of process.

KW - DSC

KW - Differential scanning calorimetry

KW - Kinetic analysis

KW - NPK

KW - Non-Parametric Kinetics

KW - Thermal decomposition

UR - http://www.scopus.com/inward/record.url?scp=33745037770&partnerID=8YFLogxK

M3 - Artículo

AN - SCOPUS:33745037770

SN - 0001-9704

VL - 62

SP - 520

EP - 524

JO - Afinidad

JF - Afinidad

IS - 519

ER -

Aplicación del método NPK a la determinación de la cinética de descomposición del triperóxido de triciclohexilideno

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